Comprehensive two-dimensional liquid chromatography and high throughput effect-directed analysis in environmental research

Boer, J. de [Promotor]Lamoree, M.H. [Copromotor]Leonards, P.E.G. [Copromotor

Effect of polymer concentration and length of hydrophobic end block on the unimer-micelle transition broadness in amphiphilic ABA symmetric triblock copolymer solutions

The effects of the length of each hydrophobic end block N_{st} and polymer concentration \bar{\phi}_{P} on the transition broadness in amphiphilic ABA symmetric triblock copolymer solutions are studied using the self-consistent field lattice model. When the system is cooled, micelles are observed, i.e.,the homogenous solution (unimer)-micelle transition occurs. When N_{st} is increased, at fixed \bar{\phi}_{P}, micelles occur at higher temperature, and the temperature-dependent range of micellar aggregation and half-width of specific heat peak for unimer-micelle transition increase monotonously. Compared with associative polymers, it is found that the magnitude of the transition broadness is determined by the ratio of hydrophobic to hydrophilic blocks, instead of chain length. When \bar{\phi}_{P} is decreased, given a large N_{st}, the temperature-dependent range of micellar aggregation and half-width of specific heat peak initially decease, and then remain nearly constant. It is shown that the transition broadness is concerned with the changes of the relative magnitudes of the eductions of nonstickers and solvents from micellar cores.Comment: 8 pages, 4 figure

Vegetation NDVI Linked to Temperature and Precipitation in the Upper Catchments of Yellow River

Vegetation in the upper catchment of Yellow River is critical for the ecological stability of the whole watershed. The dominant vegetation cover types in this region are grassland and forest, which can strongly influence the eco-environmental status of the whole watershed. The normalized difference vegetation index (NDVI) for grassland and forest has been calculated and its daily correlation models were deduced by Moderate Resolution Imaging Spectroradiometer products on 12 dates in 2000, 2003, and 2006. The responses of the NDVI values with the inter-annual grassland and forest to three climatic indices (i.e., yearly precipitation and highest and lowest temperature) were analyzed showing that, except for the lowest temperature, the yearly precipitation and highest temperature had close correlations with the NDVI values of the two vegetation communities. The value of correlation coefficients ranged from 0.815 to 0.951 (p <0.01). Furthermore, the interactions of NDVI values of vegetation with the climatic indicators at monthly interval were analyzed. The NDVI of vegetation and three climatic indices had strong positive correlations (larger than 0.733, p <0.01). The monthly correlations also provided the threshold values for the three climatic indictors, to be used for simulating vegetation growth grassland under different climate features, which is essential for the assessment of the vegetation growth and for regional environmental management

Asymptotic Matrix Theory of Bragg Fibers

We developed a matrix theory that applies to any cylindrically symmetric fiber surrounded with Bragg cladding, which includes both the Bragg fibers and the recently proposed dielectric coaxial fibers. In this formalism,an arbitrary number of inner dielectric layers are treated exactly and the outside cladding structure is approximated in the asymptotic limit. An estimate of the radiation loss of such fibers is given. We compare the asymptotic results with those obtained from the finite difference time domain (FDTD) calculations and find excellent agreement between the two approaches

The effect of asymmetry of the coil block on self-assembly in ABC coil-rod-coil triblock copolymers

Using the self-consistent field approach, the effect of asymmetry of the coil block on the microphase separation is focused in ABC coil-rod-coil triblock copolymers. For different fractions of the rod block $f_{\text B}$, some stable structures are observed, i.e., lamellae, cylinders, gyroid, and core-shell hexagonal lattice, and the phase diagrams are constructed. The calculated results show that the effect of the coil block fraction $f_{\text A}$ is dependent on $f_{\text B}$. When $f_{\text B}=0.2$, the effect of asymmetry of the coil block is similar to that of the ABC flexible triblock copolymers; When $f_{\text B}=0.4$, the self-assembly of ABC coil-rod-coil triblock copolymers behaves like rod-coil diblock copolymers under some condition. When $f_{\text B}$ continues to increase, the effect of asymmetry of the coil block reduces. For $f_{\text B}=0.4$, under the symmetrical and rather asymmetrical conditions, an increase in the interaction parameter between different components leads to different transitions between cylinders and lamellae. The results indicate some remarkable effect of the chain architecture on self-assembly, and can provide the guidance for the design and synthesis of copolymer materials.Comment: 9 pages, 3 figure

Minimal Diagnosis and Diagnosability of Discrete-Event Systems Modeled by Automata

In the last several decades, the model-based diagnosis of discrete-event systems (DESs) has increasingly become an active research topic in both control engineering and artificial intelligence. However, in contrast with the widely applied minimal diagnosis of static systems, in most approaches to the diagnosis of DESs, all possible candidate diagnoses are computed, including nonminimal candidates, which may cause intractable complexity when the number of nonminimal diagnoses is very large. According to the principle of parsimony and the principle of joint-probability distribution, generally, the minimal diagnosis of DESs is preferable to a nonminimal diagnosis. To generate more likely diagnoses, the notion of the minimal diagnosis of DESs is presented, which is supported by a minimal diagnoser for the generation of minimal diagnoses. Moreover, to either strongly or weakly decide whether a minimal set of faulty events has definitely occurred or not, two notions of minimal diagnosability are proposed. Necessary and sufficient conditions for determining the minimal diagnosability of DESs are proven. The relationships between the two types of minimal diagnosability and the classical diagnosability are analysed in depth